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Solid-liquid equilibria (solid solubilities) are of great importance not only for crystallization processes but also for the selection of solvents for reaction mixtures
and for plant safety assessment. In addition, these data provide information about the real mixture behavior at low temperatures, where the fugacity of a component cannot
be easily determined via the fugacity or partial pressure over the solution.
SLE contains 38,452 data sets (314,308 data points) from 4,834 references for 3,829 components and 20,675 different systems
(16,235 binary, 4,160 ternary and 280 quaternary
systems) (Version 2011).
Besides a large number of eutectic systems with nearly total immiscibility in the solid phase, the SLE data bank also contains data for components forming ideal or nonideal
solid mixtures as well as those that form adducts.
The following diagram shows several important types of binary
solid-liquid equilibrium behavior (all data taken from DDB-SLE):
Selected Scientific Papers
| 2009 | Prediction of solubilities of salts, osmotic coefficients and vapor-liquid equilibria for single and mixed solvent electrolyte systems using the LIQUAC model | Huang J., Li J., Gmehling J. | Journal | Fluid Phase Equilib., 275, 1, 8 20 (2009) |
| 2005 | gE Model for Single- and Mixed-Solvent Electrolyte Systems. 3. Prediction of Salt Solubilities in Aqueous Electrolyte Systems | Li J., Lin Y., Gmehling J. | Journal | Ind.Eng.Chem.Res., 44, 5, 1602 1609 (2005) |
| 2003 | The effect of gas pressure on the melting behavior of compounds | Fischer K., Wilken M., Gmehling J. | Journal | Fluid Phase Equilib., 210, 2, 199 214 (2003) |
| 1997 | Estimation of Enthalpies of Fusion, Melting Temperatures, Enthalpies of Transition, and Transition Temperatures of Pure Compounds from Experimental Binary Solid-Liquid Equilibrium Data of Eutectic Systems | Lohmann J., Joh R., Gmehling J. | Journal | J.Chem.Eng.Data, 42, 6, 1176 1180 (1997) |
| 1997 | Measurement and Prediction of Ternary Solid-Liquid Equilibria | Joh R., Kreutz J., Gmehling J. | Journal | J.Chem.Eng.Data, 42, 5, 886 889 (1997) |
| 1978 | Solid-Liquid Equilibria Using Unifac | Gmehling J.G., Anderson T.F., Prausnitz J.M. | Journal | Ind.Eng.Chem. Fundam., 17, 4, 269 273 (1978) |
Selected Scientific Papers (Experimental Data)
| 2010 | Solubility and density measurements of palmitic acid in supercritical carbon dioxide + alcohol mixtures | Brandt L., Elizalde-Solis O., Galicia-Luna L.A., Gmehling J. | Journal | Fluid Phase Equilib., 289, 1, 72 79 (2010) |
| 2008 | High pressure solid-solid and solid-liquid transition data for long chain alkanes | Machado J.J.B., de Loos T.W., Ihmels E.C., Fischer K., Gmehling J. | Journal | J.Chem.Thermodyn., 40, 12, 1632 1637 (2008) |
| 2008 | Vapour-liquid equilibria, azeotropic data, excess enthalpies, activity coefficients at infinite dilution and solid-liquid equilibria for binary alcohol-ketone systems | Abbas R., Gmehling J. | Journal | Fluid Phase Equilib., 267, 2, 119 126 (2008) |
| 2006 | Solid-Liquid Equilibria for Binary Organic Systems Containing 1-Methoxy-2-propanol and 2-Butoxy Ethanol | Negadi L., Wilken M., Gmehling J. | Journal | J.Chem.Eng.Data, 51, 5, 1873 1876 (2006) |
| 2005 | Activity Coefficient at Infinite Dilution, Azeotropic Data, Excess Enthalpies and Solid-Liquid-Equilibria for Binary Systems of Alkanes and Aromatics with Esters | Collinet E., Gmehling J. | Journal | Fluid Phase Equilib., 230, 1-2, 131-142 (2005) |
| 2003 | Azeotropic and solid - liquid equilibria data for several binary organic systems containing one acetal compound | Teodorescu M., Wilken M., Wittig R., Gmehling J. | Journal | Fluid Phase Equilib., 204, 6, 267 280 (2003) |
| 2001 | Binary Solid-Liquid equilibria of Organic Systems Containing e-Caprolactone | Wittig R., Constantinescu D., Gmehling J. | Journal | J.Chem.Eng.Data, 46, 6, 1490 1493 (2001) |
| 2001 | Binary Solid-Liquid Equilibria of N,N-Dimethylacetamide with 1,2-Dichloroethane, Dichloromethane, and 1-Propanol | Atik Z., Ahlers J., Lohmann J., Gmehling J. | Journal | J.Chem.Eng.Data, 46, 5, 1190 1192 (2001) |
| 2001 | Solid-Liquid Equilibria for Seven Binary Systems | Lohmann J., Gmehling J. | Journal | J.Chem.Eng.Data, 46, 2, 333 336 (2001) |
| 1999 | Binary Solid-Liquid Equilibria of Organic Systems Containing Different Amides and Sulfolane | Ahlers J., Lohmann J., Gmehling J. | Journal | J.Chem.Eng.Data, 44, 4, 727 730 (1999) |
| 1998 | Solid-Liquid Equilibria of Several Binary Systems with Organic Compounds | Lohmann J., Roepke T., Gmehling J. | Journal | J.Chem.Eng.Data, 43, 5, 856 860 (1998) |
| 1997 | Solid-Liquid Equilibria of Viscous Binary Mixtures with Alcohols | Lohmann J., Joh R., Gmehling J. | Journal | J.Chem.Eng.Data, 42, 6, 1170 1175 (1997) |
| 1996 | Solid-Liquid Equilibria for Different Heptanones with Benzene, Cyclohexane, and Ethanol | Fiege C., Joh R., Petri M., Gmehling J. | Journal | J.Chem.Eng.Data, 41, 6, 1431 1433 (1996) |
| 1995 | Solid-liquid equilibria in binary mixtures of organic compounds | Jakob A., Joh R., Rose C., Gmehling J. | Journal | Fluid Phase Equilib., 113, 5, 117 125 (1995) |
| 1994 | Excess Volumes for Alkanol + Morpholine Systems at 298.15 and 308.15 K | Park S.-J., Fischer K., Gmehling J. | Journal | J.Chem.Eng.Data, 39, 4, 859 862 (1994) |
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