Dortmund Data Bank

Vapor-Liquid Equilibrium Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.

Vapor-Liquid Equilibrium Data Set 2919

Components

No. Formula Molar Mass CAS Registry Number Name
1 C2H6O 46.069 64-17-5 Ethanol
2 H2O 18.015 7732-18-5 Water
3 C4H10O 74.123 71-36-3 1-Butanol
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Constant Value

Pressure 101.33 kPa

Data Table

T [K] x1 [mol/mol] x2 [mol/mol] y1 [mol/mol] y2 [mol/mol]
355.20 0.16600 0.82590 0.56500 0.41400
353.41 0.28800 0.70500 0.65800 0.33670
351.71 0.64600 0.34990 0.79250 0.20680
360.59 0.05230 0.93820 0.37400 0.55130
361.67 0.03390 0.95640 0.26400 0.62400
364.43 0.01650 0.97380 0.14050 0.73000
353.69 0.30200 0.67590 0.58750 0.39900
352.75 0.46150 0.52000 0.65100 0.34070
351.77 0.66460 0.32400 0.79300 0.20510
360.63 0.12900 0.62300 0.25300 0.61200
359.95 0.08900 0.84300 0.31400 0.57900
354.62 0.32200 0.62730 0.62200 0.35610
351.84 0.68400 0.29200 0.77660 0.21800
360.39 0.09950 0.78550 0.30600 0.57600
357.59 0.21200 0.68700 0.48900 0.44100
354.91 0.35300 0.56400 0.56700 0.40630
353.36 0.51200 0.42540 0.63100 0.35500
353.86 0.58700 0.29300 0.69700 0.27610
351.95 0.77000 0.16380 0.85600 0.13320
352.15 0.81330 0.09800 0.87300 0.11180
358.26 0.26200 0.52900 0.44300 0.46450
362.93 0.07300 0.53600 0.15000 0.65100
361.13 0.14880 0.49320 0.25400 0.59650
357.41 0.30300 0.40400 0.43250 0.48070
355.10 0.46800 0.30900 0.61770 0.33200
363.72 0.13700 0.32400 0.22450 0.56000
362.09 0.18500 0.30650 0.30200 0.52500
357.23 0.35600 0.24400 0.52140 0.38900
368.61 0.05600 0.14000 0.13000 0.49500
363.61 0.16300 0.12500 0.36600 0.42500
357.48 0.40700 0.08960 0.66500 0.23900
355.34 0.58400 0.06000 0.79300 0.15550

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Frolov A.F.; Karaseva A.P.; Loginova M.A.: Dampf-Flüssig-Gleichgewicht im System Ethanol - n-Butanol - Wasser. Book: Fiz.Khim.Rastvorov (1972) 217-223


Vapor-Liquid Equilibrium Data Set 5039

Components

No. Formula Molar Mass CAS Registry Number Name
1 H2O 18.015 7732-18-5 Water
2 C4H10O 74.123 71-36-3 1-Butanol
3 C2H6O 46.069 64-17-5 Ethanol
Search the DDB for all data of this mixture

Constant Value

Pressure 101.33 kPa

Data Table

x1 [mol/mol] x2 [mol/mol] y1 [mol/mol] y2 [mol/mol]
0.98700 0.00005 0.87800 0.00092
0.98700 0.00001 0.85700 0.00869
0.98300 0.00020 0.85500 0.00318
0.97500 0.00005 0.81400 0.00070
0.97100 0.00011 0.77200 0.00168
0.97000 0.00036 0.76700 0.00459
0.96000 0.00032 0.74000 0.00350
0.95300 0.00010 0.69800 0.00114
0.94900 0.00022 0.67700 0.00242
0.94800 0.00024 0.68600 0.00241
0.94700 0.00072 0.66300 0.00755
0.93100 0.00064 0.62200 0.00520
0.91900 0.00143 0.60200 0.01170
0.88300 0.00129 0.54500 0.00629
0.86100 0.00048 0.50900 0.00165
0.83600 0.00215 0.50000 0.00544
0.82200 0.00067 0.48800 0.00160
0.79800 0.00258 0.48400 0.00490
0.79500 0.00255 0.46500 0.00472
0.77500 0.00027 0.46300 0.00041
0.74300 0.00328 0.45500 0.00431
0.72300 0.00172 0.44500 0.00200
0.71100 0.00333 0.44200 0.00349
0.71000 0.00175 0.42800 0.00189
0.70600 0.00230 0.43000 0.00230
0.70200 0.00141 0.43200 0.00138
0.69700 0.00359 0.42900 0.00348
0.67700 0.00346 0.41500 0.00313
0.62500 0.00384 0.39700 0.00276
0.61000 0.00126 0.38900 0.00084
0.56400 0.00375 0.37400 0.00221
0.52700 0.00352 0.36000 0.00182
0.45500 0.00418 0.33100 0.00188
0.43500 0.00699 0.31500 0.00276
0.43100 0.00369 0.31400 0.00147
0.41100 0.00355 0.30800 0.00140
0.39900 0.00316 0.29800 0.00117
0.38100 0.00277 0.29200 0.00099
0.35400 0.00284 0.28400 0.00097
0.33500 0.00212 0.27700 0.00072
0.25200 0.00197 0.20300 0.00058
0.24700 0.00107 0.19900 0.00031
0.23000 0.00151 0.19500 0.00048
0.19400 0.00200 0.17700 0.00057
0.17500 0.00390 0.16300 0.00108
0.16100 0.00500 0.16100 0.00131
0.15700 0.00161 0.14900 0.00050
0.15500 0.00125 0.14800 0.00034
0.08800 0.00187 0.09800 0.00049
0.08300 0.00518 0.09000 0.00130
0.07900 0.00344 0.08800 0.00075
0.07600 0.00932 0.08500 0.00235
0.01800 0.00321 0.02200 0.00081

(x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Ikari A.; Ayabe N.: On the Vapor-Liquid Equilibrium of Minute Amount Component-Water-Ethanol System Containing a Minute Amount of 1-Butanol. Kagaku Kogaku 33 (1969) 157-162


Vapor-Liquid Equilibrium Data Set 5111

Components

No. Formula Molar Mass CAS Registry Number Name
1 C2H6O 46.069 64-17-5 Ethanol
2 C4H10O 74.123 71-36-3 1-Butanol
3 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Constant Value

Pressure 102.23 kPa

Data Table

T [K] x1 [mol/mol] x2 [mol/mol] y1 [mol/mol] y2 [mol/mol]
363.91 0.03410 0.08360 0.11840 0.18310
363.98 0.04290 0.12870 0.11760 0.18400
363.79 0.04180 0.09350 0.13000 0.17900
363.72 0.05220 0.13950 0.13170 0.17930
362.67 0.06500 0.08320 0.19220 0.14980
359.89 0.10150 0.06410 0.28490 0.11200
359.91 0.12660 0.06050 0.32730 0.09130
358.93 0.16100 0.05760 0.37710 0.07360
357.90 0.20490 0.05430 0.42340 0.05770

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Newsham D.M.T.; Vahdat N.: Part I: Experimental Results for the Systems Methanol-Water-n-Butanol, Ethanol-Water-n-Butanol and n-Propanol-Water-n-Butanol. Chem.Eng.J. 13 (1977) 27-31

List of All References

Source

Vapor-Liquid Equilibrium Data Overview


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