Dortmund Data Bank

Vapor-Liquid Equilibrium Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.

Vapor-Liquid Equilibrium Data Set 1133

Components

No. Formula Molar Mass CAS Registry Number Name
1 H2O 18.015 7732-18-5 Water
2 C4H10O 74.123 71-36-3 1-Butanol
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Constant Value

Pressure 101.33 kPa

Data Table

T [K] x1 [mol/mol] y1 [mol/mol]
384.65 0.03900 0.26700
383.75 0.04700 0.29900
382.75 0.05500 0.32300
381.95 0.07000 0.35200
371.05 0.25700 0.62900
370.35 0.27500 0.64100
369.85 0.29200 0.65500
369.45 0.30500 0.66200
366.65 0.49600 0.73600
366.55 0.50600 0.74000
366.05 0.55200 0.75000
366.05 0.56400 0.75200
366.05 0.57100 0.74800
365.95 0.57700 0.75000
365.85 0.97500 0.75200
366.15 0.98000 0.75600
365.95 0.98200 0.75800
366.55 0.98500 0.77500
366.55 0.98600 0.78400
366.85 0.98800 0.80800
368.55 0.99200 0.84300
369.95 0.99400 0.88400
371.45 0.99700 0.92900
371.55 0.99800 0.95100
372.55 0.99900 0.98100

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Stockhardt J.S.; Hull C.M.: Vapor-Liquid Equilibria and Boiling-Point Composition Relations for Systems n-Butanol-Water and Isobutanol-Water. Ind.Eng.Chem. Ind.Ed. 23 (1931) 1438-1440


Vapor-Liquid Equilibrium Data Set 1134

Components

No. Formula Molar Mass CAS Registry Number Name
1 H2O 18.015 7732-18-5 Water
2 C4H10O 74.123 71-36-3 1-Butanol
Search the DDB for all data of this mixture

Constant Value

Temperature 298.15 K

Data Table

P [kPa] x1 [mol/mol] y1 [mol/mol]
0.928 0.00000 0.00000
2.557 0.15000 0.68820
3.409 0.30000 0.79000
3.716 0.51240 0.82530
3.716 0.98120 0.82530
3.516 0.99000 0.88740

(P - pressure, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Butler J.A.V.; Thomson D.W.; MacLennan W.N.: Part III. The Theory of Binary Solutions, and its Application to Aqueous-Alcoholic Solutions.. J.Chem.Soc.London (1933) 674-686


Vapor-Liquid Equilibrium Data Set 1135

Components

No. Formula Molar Mass CAS Registry Number Name
1 H2O 18.015 7732-18-5 Water
2 C4H10O 74.123 71-36-3 1-Butanol
Search the DDB for all data of this mixture

Constant Value

Pressure 102.26 kPa

Data Table

T [K] x1 [mol/mol] y1 [mol/mol]
384.10 0.05000 0.25300
380.00 0.09200 0.38800
379.55 0.09700 0.40200
374.00 0.18100 0.55600
369.80 0.29100 0.66000
369.50 0.30300 0.66600
367.15 0.41700 0.72400
366.17 0.54600 0.75000
366.15 0.55000 0.75300
365.85 0.75200 0.75400
365.91 0.90200 0.75400
365.95 0.98000 0.76000
366.00 0.98100 0.76300
368.55 0.99100 0.83900
368.95 0.99200 0.85000

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Smith T.E.; Bonner R.F.: Vapor-Liquid Equilibrium Still for Partially Miscible Liquids. Ind.Eng.Chem. 41 (1949) 2867-2871

Diagrams

Vapor-Liquid Equilibrium of 1-Butanol+Water
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Vapor-Liquid Equilibrium of 1-Butanol+Water
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Vapor-Liquid Equilibrium of 1-Butanol+Water
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Vapor-Liquid Equilibrium of 1-Butanol+Water
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List of All References

Source
Butler J.A.V.; Thomson D.W.; MacLennan W.N.: Part III. The Theory of Binary Solutions, and its Application to Aqueous-Alcoholic Solutions.. J.Chem.Soc.London (1933) 674-686
Stockhardt J.S.; Hull C.M.: Vapor-Liquid Equilibria and Boiling-Point Composition Relations for Systems n-Butanol-Water and Isobutanol-Water. Ind.Eng.Chem. Ind.Ed. 23 (1931) 1438-1440
Smith T.E.; Bonner R.F.: Vapor-Liquid Equilibrium Still for Partially Miscible Liquids. Ind.Eng.Chem. 41 (1949) 2867-2871

Vapor-Liquid Equilibrium Data Overview


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